• 
  Anthony Hopkins

  Pierre Bezukhov (17 episodes, 1972-1973)
• 
  Barbara Lott

  Nadia Galenkova (1 episode, 1973)
• 
  Kevin Stoney

  Marshal Benningsen (1 episode, 1972)
• 
  Tenniel Evans

  Prince Bagration (2 episodes, 1972)
• 
  Patrick Holt

  Uncle (1 episode, 1972)
• 
  Edith Sharpe

  Madame Scherer (2 episodes, 1972)
• 
  Rollo Gamble

  Yermolov (1 episode, 1972)
• 
  Sylvester Morand

  Nikolai Rostov (10 episodes, 1972-1973)

• 
  Richard Beale

  Hetman (1 episode, 1973)
• 
  Michael Mulcaster

  Gen. Mack (1 episode, 1972)
• 
  Joanna David

  Sonya (13 episodes, 1972-1973)
• 
  Basil Dignam

  Speransky (1 episode, 1972)
• 
  Michael Billington

  Lt. Berg (4 episodes, 1972)
• 
  Basil Henson

  Prince Vasili Kuragin (4 episodes, 1972-1973)
• 
  Michael Gover

  Gen. Balshev (1 episode, 1972)

• 
  Brian Vaughan

  Petrov (1 episode, 1973)
• 
  Faith Brook

  Countess Rostova (12 episodes, 1972-1973)
• 
  Athene Fielding

  Amelie Bourienne (6 episodes, 1972)
• 
  Tony Caunter

  French Corporal (2 episodes, 1973)
• 
  Jack Galloway

  Prison guard (1 episode, 1973)
• 
  Victor Brooks

  Dron (1 episode, 1972)
• 
  Anthony Jacobs

  Prince Bolkonsky (7 episodes, 1972)